全文获取类型
收费全文 | 511篇 |
免费 | 34篇 |
国内免费 | 1篇 |
专业分类
化学 | 386篇 |
晶体学 | 2篇 |
力学 | 17篇 |
数学 | 36篇 |
物理学 | 105篇 |
出版年
2023年 | 3篇 |
2022年 | 2篇 |
2021年 | 22篇 |
2020年 | 19篇 |
2019年 | 18篇 |
2018年 | 16篇 |
2017年 | 15篇 |
2016年 | 42篇 |
2015年 | 20篇 |
2014年 | 28篇 |
2013年 | 72篇 |
2012年 | 31篇 |
2011年 | 33篇 |
2010年 | 16篇 |
2009年 | 20篇 |
2008年 | 32篇 |
2007年 | 23篇 |
2006年 | 20篇 |
2005年 | 23篇 |
2004年 | 18篇 |
2003年 | 14篇 |
2002年 | 8篇 |
2001年 | 6篇 |
2000年 | 1篇 |
1999年 | 1篇 |
1997年 | 2篇 |
1996年 | 4篇 |
1995年 | 2篇 |
1994年 | 1篇 |
1993年 | 2篇 |
1992年 | 2篇 |
1991年 | 3篇 |
1990年 | 1篇 |
1989年 | 3篇 |
1988年 | 1篇 |
1986年 | 2篇 |
1985年 | 3篇 |
1984年 | 1篇 |
1983年 | 1篇 |
1982年 | 3篇 |
1981年 | 1篇 |
1980年 | 1篇 |
1978年 | 3篇 |
1977年 | 2篇 |
1974年 | 1篇 |
1973年 | 3篇 |
1963年 | 1篇 |
排序方式: 共有546条查询结果,搜索用时 17 毫秒
101.
Quantitative structure–property relationships of retention indices of some sulfur organic compounds using random forest technique as a variable selection and modeling method 下载免费PDF全文
102.
103.
104.
Salim A. Messaoudi Nasser‐eddine Tatar 《Mathematical Methods in the Applied Sciences》2007,30(6):665-680
In this paper the nonlinear viscoelastic wave equation in canonical form with Dirichlet boundary condition is considered. By introducing a new functional and using the potential well method, we show that the damping induced by the viscoelastic term is enough to ensure global existence and uniform decay of solutions provided that the initial data are in some stable set. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
105.
Preparation and coordination complex of the first imine-bridged tetrathiafulvalene-pyridine donor ligand 总被引:1,自引:0,他引:1
Chahma M Hassan N Alberola A Stoeckli-Evans H Pilkington M 《Inorganic chemistry》2007,46(10):3807-3809
The first imine-bridged pyridyltetrathiafulvalene building block (TTF-CH=N-Py, 1) has been synthesized via the Schiff base condensation of formyltetrathiafulvalene and 2-aminopyridine. The preparation, X-ray crystal structure, electrochemical and magnetic characterization of a 1:1 copper complex [CuII(hfac)2(TTF-CH=N-Py)] (2) are reported. The crystal structure reveals that the imine N atom participates in chelation to the paramagnetic center, thus making this ligand an attractive precursor for the assembly of pi-d systems. 相似文献
106.
Nasser?Mohammed?HosnyEmail author Abdel-Hamid?M.?Shallaby 《Transition Metal Chemistry》2007,32(8):1085-1090
Coordination compounds of MnII, CuII, FeIII and ZnII ions with 4-acetylpyridine nicotinoylhydrazone (4-APNH) were synthesized and characterized by elemental analyses, molar conductivity,
magnetic moments, i.r., u.v./vis., m.s., 1H-n.m.r. and thermal analyses. I.r. spectra show that the ligand can act either in the enol form as monovalent bidentate or
in the keto form as neutral bidentate depending on the metal salt used. Octahedral structures are proposed for Fe complex
and square – planar for the Cu complex, while tetrahedral structures were suggested for Zn and Mn complexes on the basis of
magnetic and spectral evidences. Semi-empirical calculations ZINDO/1 have been used to study the molecular geometry and the
harmonic vibrational spectra with the purpose to assist the experimental assignment of the complexes.
In memory of the late Professor Dr. Abdel Hamid M. Shallaby 2/5/2006 相似文献
107.
In this article, the propagation of an intense laser pulse through underdense collisional plasma in the presence of planar magnetostatic wiggler is studied. It is shown that the electron density distribution, in the presence of planar wiggler with increasing of the normalized plasma length, increases initially and then reaches a peak for different values of wiggler amplitudes. In addition, it is found that the existence of wiggler field leads to an increase in the electron density distribution and subsequently enhancement of electric field. Moreover, it is observed that by increasing the wiggler field, as a result of the increase of the electron density distribution, the dielectric permittivity constant is reduced. It is seen that while wiggler magnetic field was applied appropriately, the total absorption coefficient in the underdense collisional isothermal magnetized plasma improves. In fact, increase of wiggler magnetic field causes the enhancement of the total absorption coefficient of plasma medium. 相似文献
108.
Generic axiomatic-nonextensive statistics introduces two asymptotic properties,to each of which a scaling function is assigned.The first and second scaling properties are characterized by the exponents c and d,respectively.In the thermodynamic limit,a grand-canonical ensemble can be formulated.The thermodynamic properties of a relativistic ideal gas of hadron resonances are studied,analytically.It is found that this generic statistics satisfies the requirements of the equilibrium thermodynamics.Essential aspects of the thermodynamic self-consistency are clarified.Analytical expressions are proposed for the statistical fits of various transverse momentum distributions measured in most-central collisions at different collision energies and colliding systems.Estimations for the freezeout temperature(T_(ch)) and the baryon chemical potential(μ_b) and the exponents c and d are determined.The earlier are found compatible with the parameters deduced from Boltzmann-Gibbs(BG) statistics(extensive),while the latter refer to generic nonextensivities.The resulting equivalence class(c,d) is associated with stretched exponentials,where Lambert function reaches its asymptotic stability.In some measurements,the resulting nonextensive entropy is linearly composed on extensive entropies.Apart from power-scaling,the particle ratios and yields are excellent quantities to highlighting whether the particle production takes place(non)extensively.Various particle ratios and yields measured by the STAR experiment in central collisions at 200,62.4 and 7.7 GeV are fitted with this novel approach.We found that both c and d 1,i.e.referring to neither BG-nor Tsallis-type statistics,but to(c,d)-entropy,where Lambert functions exponentially rise.The freezeout temperature and baryon chemical potential are found comparable with the ones deduced from BG statistics(extensive).We conclude that the particle production at STAR energies is likely a nonextensive process but not necessarily BG or Tsallis type. 相似文献
109.
Ahmad Aqel Abdulrhman M. Dhabbah Kareem Yusuf Nasser M. AL-Harbi Zeid A. Al Othman A. Yacine Badjah-Hadj-Ahmed 《Journal of Analytical Chemistry》2016,71(7):730-736
The identification of ignitable liquids is very important and challenging aspect in arson crime investigations. The detection of gasoline and diesel fuel components using solid phase micro-extraction prior to gas chromatography–mass spectrometry for the forensic analysis of fire debris has been carried out. Previous works show that the absorption characteristics of the substrate are one of the most important factors in determining the evaporation rate of the accelerants. In order to determine the presence of the fuel residues, four of the most common substrate materials were tested in this work; wool, cotton, silk and polyester. The obtained results indicate that both gasoline and diesel fuel accelerants persisted longer on wool and silk than on the other selected substrates. Such information illustrates the influence of fuel persistence times after extinguishing and the best materials to be scanned for ignitable liquids at the fire scene. 相似文献
110.
This paper develops a multi-parturition genetic algorithm (MPGA) to be used in geometrical bounding of the overlapped clusters in a data set for the classification of chemical data. Two new operators have been introduced to modify the conventional genetic algorithm, namely, multi-parturition and decimation and orientated creation to improve the linear classification results and diminish the computational time. To circumvent the difficulty commonly encountered in the treatment of linearly inseparable chemical data sets, the optimized linear classifier is further modified to provide a complementary nonlinear classifier. For this reason the space regions of the overlapped clusters have been bounded by erection of half-hyperellipsoids over the linearly misclassified patterns. The proposed MPGA was applied to classify a number of chemical and other data sets with a dimension from 4 to 14. Experimental results have indicated that the proposed MPGA could classify seriously overlapped data sets with an acceptable error rate. 相似文献